Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl.

نویسندگان

  • Leila R Hill
  • Octavia A Blackburn
  • Michael W Jones
  • Manuel Tropiano
  • Thomas Just Sørensen
  • Stephen Faulkner
چکیده

The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis(Eu·DO3A)-5-amino-m-xylene.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 46  شماره 

صفحات  -

تاریخ انتشار 2013